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        Naming inorganic compounds

            metal containing

            Compounds containing a metal will be based on the name of the elemental metal plus the name of the anion. The name of simple nonmetal anions convert the ending of the element name with -ide. Polyatomic anions usually end with -ite or -ate. (Note that hydroxide, OH-, is an exception.)

            F- fluoride

            Cl- chloride ClO2- chlorite ClO32- chlorate ClO4- perchlorate

            Br- bromide BrO32- bromate

            I- iodide IO32- iodate

            O2- oxide OH- hydroxide O22- peroxide

            S2- sulfide SO32- sulfite SO42- sulfate

            Se2- selenide

            N3- nitride NO2- nitrite NO3- nitrate

            P3- phosphide PO43- phosphate

            As3- arsenide AsO32- arsenate

            C4- carbide CO32- carbonate

            Si4- silicide SiO44- silicate

            a few more

            HCO3- hydrogen carbonate (bicarbonate)

            HSO3- hydrogen sulfite (bisulfite)

            HSO4- hydrogen sulfate (bisulfate)

            HPO42- hydrogen phosphate

            H2PO4- dihydrogen phosphate

            common organic anions

            CH3COO- acetate

            HCOO- formate

            C2O42- oxalate

            common anions containing metals

            MnO4- permanganate

            CrO42- chromate

            Cr2O72- dichromate

            Metals with multiple oxidation states use a Roman numeral in parentheses to specify the oxidation state. Example:

            formula write as read as

            FeCl2 iron(II) chloride iron two chloride

            FeCl3 iron(III) chloride iron three chloride

            nonmetals

            The name of nonmetallic compounds use the name of the first element in the formula followed by the name for the other elements in the compound, modified as above. A prefix indicates the number of each atom in the compound. Examples:

            formula read as

            CO carbon monoxide

            CO2 carbon dioxide

            SO2 sulfur dioxide

            SO3 sulfur trioxide

            N2O5 dinitrogen pentoxide

            Naming Complexes

            Complex ions are named with the ligand names added as prefixes to the name of the central metal ion. Anionic ligands are modified with the suffix -o, for example: chloro, Cl-, cyano, CN-, and hydroxo, OH-. Most neutral ligands retain their usual name, a few exceptions are:

            formula ligand name

            C=O carbonyl

            H2O aqua

            NH3 ammine

            formula read as

            Cu(H2O)42- tetraaquacopper(II)

            CoCl63- hexachlorocobalt(III)

         

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